Scientific Methods: Significant figures

There are two kinds of numbers in the world:


PRECISION VERSUS ACCURACY

Accuracy refers to how closely a measured value agrees with the correct value.
Precision refers to how closely individual measurements agree with each other.

accurate
(the average is accurate)
not precise
precise
not accurate
accurate
and
precise


In any measurement, the number of significant figures is critical. The number of significant figures is the number of digits believed to be correct by the person doing the measuring. It includes one estimated digit.

A rule of thumb: read a measurement to 1/10 or 0.1 of the smallest division. This means that the error in reading (called the reading error) is 1/10 or 0.1 of the smallest division on the ruler or other instrument. If you are less sure of yourself, you can read to 1/5 or 0.2 of the smallest division.

Rules for Significant Figures:

  1. Leading zeros are never significant.
    Imbedded zeros are always significant.
    Trailing zeros are significant only if the decimal point is specified.
    Hint: Change the number to scientific notation. It is easier to see.

  2. Addition or Subtraction:
    The last digit retained is set by the first doubtful digit.

  3. Multiplication or Division:
    The answer contains no more significant figures than the least accurately known number.

EXAMPLES:

Example Number of
Significant Figures
Scientific Notation
0.0068236.82 x 10 -3Leading zeros are not significant.
1.07241.072 (x 10 0)Imbedded zeros are always significant.
30013 x 102 Trailing zeroes are significant only if the decimal point is specified.
300.3 3.00 x 102
300.04 3.000 x 102

EXAMPLES
Addition Even though your calculator gives you the answer 8.0372, you must round off to 8.04. Your answer must only contain 1 doubtful number. Note that the doubtful digits are underlined.
Subtraction Subtraction is interesting when concerned with significant figures. Even though both numbers involved in the subtraction have 5 significant figures, the answer only has 3 significant figures when rounded correctly. Remember, the answer must only have 1 doubtful digit.
MultiplicationThe answer must be rounded off to 2 significant figures, since 1.6 only has 2 significant figures.
DivisionThe answer must be rounded off to 3 significant figures, since 45.2 has only 3 significant figures.

Notes on Rounding


QUIZ:
Question 1Give the correct number of significant figures for 4500, 4500., 0.0032, 0.04050
Question 2Give the answer to the correct number of significant figures:
4503 + 34.90 + 550 = ?
Question 3Give the answer to the correct number of significant figures:
1.367 - 1.34 = ?
Question 4Give the answer to the correct number of significant figures:
(1.3 x 103)(5.724 x 104) = ?
Question 5Give the answer to the correct number of significant figures:
(6305)/(0.010) = ?

Answers: (1) 2, 4, 2, 4 (2) 5090 (3 significant figures - round to the tens place - set by 550) (3) 0.03 (1 significant figure - round to hundredths place) (4) 7.4 x 107 (2 significant figures - set by 1.3 x 103) (5) 6.3 x 105 (2 significant figures - set by 0.010)

This page adapted from a math review for chemistry students at Texas A&M University